S A F E T Y    D A T A   S H E E T

according to Regulation (EC) No. 1907/2006 (amended by Regulation (EU) 2015/830)

Pepper spray

SECTION 1: Identification of the substance/mixture and of the company/undertaking

• Product identifier

Product name Product code

Protect Human Self-Defense Pepper Spray None.

• Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture Protect Human Self-Defense Pepper Spray
• Details of the supplier of the safety data sheet

Company/Undertaking Identification

• Emergency telephone number

Issuing date Version

Protect Humans

Add: 444 N. Harper St. LA CA 90048

Phone: +1 (310) 592-5258

08.06.2020

GHS 1

SECTION 2: Hazards identification

• Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008

Additional information

• Label elements

Signal Word Hazard Statements

Precautionary statements

Supplemental information Product identifier

• Other hazards

Serious eye damage/eye irritation, Cat. 2, H319 Aerosols, Cat. 1, H222 H229

For the full text of the phrases mentioned in this Section, see Section 16.

Danger

H222: Extremely flammable aerosol.

H229: Pressurised container: May burst if heated. H319: Causes serious eye irritation.

P210b: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211: Do not spray on an open flame or other ignition source. P251: Do not pierce or burn, even after use.

P410+P412: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.

P102: Keep out of reach of children.

P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313: If eye irritation persists: Get medical advice/ attention.

None. None.

None known.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

For the full text of the phrases mentioned in this Section, see Section 16.

Hazardous impurities                        None known.

SECTION 4: First aid measures

• Description of first aid measures

Inhalation                                         Move to fresh air. Consult a physician for severe cases.

Skin contact                                      Wash off immediately with plenty of water. If skin irritation persists, call a physician.

Eye contact

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Protect unharmed eye. Consult an ophthalmologist.

Ingestion                                          Clean mouth with water and drink afterwards plenty of water.

Prevent vomiting if possible.

• Most important symptoms Cramp-like swelling eyelids, watery eyes, sneezing and acute

and effects, both acute and              cough (nausea) and strong burning sensation on the skin.

delayed

• Indication of any immediate medical attention and special

treatment needed

None known.

SECTION 5: Firefighting measures

• Extinguishing media

Suitable extinguishing media

Extinguishing media which must not be used for safety reasons

• Special hazards arising from the substance or mixture

Use dry chemical, CO2, water spray or alcohol foam . High volume water jet.

During a fire, smoke may contain the original material in addition to unidentified toxic and/or irritating compounds. Closed containers may explode due to pressure build-up when subjected to excessive heat or intense fire.

• Advice for firefighters

Special protective equipment for firefighters

Standard procedure for chemical fires.

Specific methods                                Water mist may be used to cool closed containers.

SECTION 6: Accidental release measures

• Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel

Advice for emergency responders

• Environmental precautions

• Methods and material for containment and cleaning up

• Reference to other sections

Avoid contact with skin and eyes. Do not breathe vapours or spray mist.

Use personal protective equipment. Ventilate the area. In the case of vapour formation use a respirator with filter model AX.

Do not flush into surface water or sanitary sewer system .

Soak up with inert absorbent material (e. g. sand, silica gel, acid binder, universal binder, sawdust). After cleaning, flush away traces with water.

See chapter 8 and 13.

SECTION 7: Handling and storage

• Precautions for safe handling

• Conditions for safe storage, including any incompatibilities

• Specific end use(s)

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Avoid contact with skin and eyes. Do not breathe vapours or spray mist.

Store in a place accessible by authorized persons only. Store in a cool and shaded area.

No information available.

SECTION 8: Exposure controls/personal protection

• Control parameters

Exposure limit(s)                                No data is available on the product itself.

Butane (CAS 106-97-8)

United Kingdom - Workplace                 750 ppm STEL Exposure Limits (WELs) - STELs                          1810 mg/m3 STEL United Kingdom - Workplace                           600 ppm TWA Exposure Limits (WELs) - TWAs                           1450 mg/m3 TWA

United Kingdom - Workplace                Capable of causing cancer and/or heritable genetic damage Exposure Limits (WELs) -                                    (containing >0.1% Buta-1,3-diene)

Carcinogens

propan-2-ol (CAS 67-63-0)

United Kingdom - Workplace                500 ppm STEL Exposure Limits (WELs) - STELs                          1250 mg/m3 STEL United Kingdom - Workplace                           400 ppm TWA

Exposure Limits (WELs) - TWAs          999 mg/m3 TWA

• Exposure controls

Appropriate engineering controls     Handle in accordance with good industrial hygiene and safety

practice.

Personal protection equipment

Respiratory protection                         In case of insufficient ventilation wear suitable respiratory

equipment. Respirator with combination filter for vapour/particulate (EN 14387).

Hand protection                                  PVC or other plastic material gloves. The selected protective gloves have to satisfy the specifications of EU Directive 89/ 686/ EEC and the standard EN 374 derived from it.

Eye protection                                    Safety glasses with side-shields conforming to EN166.

Skin and body protection                     No special measures required.

Thermal hazards                                 Container may rupture on heating. Keep product and empty container away from heat and sources of ignition.

Environmental exposure controls     No special measures required.

SECTION 9: Physical and chemical properties

• Information on basic physical and chemical properties

Appearance Colour Odour

Odour Threshold pH:

Melting point/range: Boiling point/range: Flash point: Evaporation Rate: Flammability: Explosion limits: Vapour pressure: Vapor density: Relative density:

Water solubility: Partition coefficient ( n- octanol/water):

Autoignition temperature: Decomposition temperature: Viscosity:

Explosive properties: Oxidising properties:

Aerosol. Clear.

Stinging.

Not determined. not applicable Not determined. Not determined.

extremely flammable Not determined.

Not determined.

Not determined. Not determined. Not determined. Not determined. partly miscible. Not determined.

Not determined. Not determined. Not determined.

Gas under pressure None

• Other information

General Product Characteristics       No information available.

SECTION 10: Stability and reactivity

• Reactivity No information

• Chemical stability Risk of receptacle
• Possibility of hazardous No information

reactions

• Conditions to avoid Burning produces obnoxious and toxic Heat, flames and

sparks.

• Incompatible materials

• Hazardous decomposition products

None under normal use.

SECTION 11: Toxicological information

• Information on toxicological effects

Acute toxicity                                    Propane (CAS 74-98-6)

Inhalation LC50 Rat = 658 mg/L 4 h(IUCLID)

Butane (CAS 106-97-8)

Inhalation LC50 Rat = 658 g/m3 4 h(NLM_CIP)

propan-2- ol; isopropyl alcohol; isopropanol (CAS 67-63-0)

Dermal LD50 Rabbit = 4059 mg/kg (JAPAN_GHS) Inhalation LC50 Rat = 72600 mg/m3 4 h(JAPAN_GHS) Oral LD50 Rat = 1870 mg/kg (JAPAN_GHS) Capsicum oleoresin (CAS 8023-77-6)

Inhalation LC50 Rat > 10000 g/m3 4 h(NLM_CIP) Oral LD50 Rat > 3 g/kg (NLM_CIP)

Skin corrosion/irritation                     Causes skin irritation.

Serious eye damage/eye                   Causes serious eye irritation.

irritation

Respiratory / Skin Sensitisation        None.

Carcinogenicity                                 Carcinogenicity classification not possible from current data.

Germ cell mutagenicity                     Fertility classification not possible from current data.

Reproductive toxicity                        Embryotoxicity classification not possible from current data.

Specific target organ toxicity            No data available.

(single exposure)

Specific target organ toxicity            No data available.

(repeated exposure)

Aspiration hazard                             No data available.

Human experience                            Cramp-like swelling eyelids, watery eyes, sneezing and acute

cough (nausea) and strong burning sensation on the skin.

SECTION 12: Ecological information

• Toxicity

propan-2-ol (CAS 67-63-0) Ecotoxicity - Freshwater Fish - Acute Toxicity Data

Ecotoxicity - Water Flea - Acute Toxicity Data

Ecotoxicity - Freshwater Algae - Acute Toxicity Data

• Persistence and degradability
• Bioaccumulative potential

• Mobility in soil

• Results of PBT and vPvB assessment

• Other adverse effects

No data is available on the product itself.

LC50 96 h Pimephales promelas 9640 mg/L [flow-through] (IUCLID) LC50 96 h Pimephales promelas 11130 mg/L [static] (IUCLID)

LC50 96 h Lepomis macrochirus >1400000 µg/L (EPA) EC50 48 h Daphnia magna 13299 mg/L (IUCLID)

EC50 96 h Desmodesmus subspicatus >1000 mg/L (IUCLID) EC50 72 h Desmodesmus subspicatus >1000 mg/L (IUCLID)

Expected to be biodegradable.

Bioaccumulation is unlikely. No data available.

No information available.

No information available.

SECTION 13: Disposal considerations

• Waste treatment methods

Waste from residues / unused products

Contaminated packaging

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on naked flame or any incandescent material.

Offer rinsed packaging material to local recycling facilities.

SECTION 14: Transport information

ADR/RID                                            UN 1950.

Proper shipping name: AEROSOLS, flammable. Class 2.

ADR/RID-Labels 2.1. Classification code 5F. Limited quantity 1 L. Excepted quantity E0. Tunnel restriction code D

IMDG

IATA

Inland navigation ADN

Further Information

UN 1950.

Proper shipping name: AEROSOLS, flammable. Class 2.

IMDG-Labels 2.1. Limited quantity 1 L. Excepted quantity E0. EmS F-D, S-U.

Marine pollutant: No.

UN 1950.

Proper shipping name: Aerosols, flammable. Class 2.

IATA label 2.1.

Packing instruction (passenger aircraft): 203 (75 kg).

Packing instruction (LQ): Y203 (30 kg G). Packing instruction (cargo aircraft): 203 (150 kg).

UN 1950.

Proper shipping name: AEROSOLS, flammable. Class 2.

ADN labels 2.1. Classification code 5F. Limited quantity 1 L. Excepted quantity E0. None.

SECTION 15: Regulatory information

• Safety, health and environmental regulations/legislation specific for the substance or mixture Regulatory Information Pressurized Protect from sunlight and do not expose to

temperatures exceeding 50 °C.

Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material.

The product is classified and labelled according to Regulation (EC) No. 1272/2008.

Propane (CAS 74-98-6)

EU - REACH (1907/2006) - List of

Registered Substances

Butane (CAS 106-97-8)

EU - REACH (1907/2006) - List of

Registered Substances

propan-2-ol (CAS 67-63-0)

EU - REACH (1907/2006) - List of

Registered Substances

Present

Present

Present

• Chemical safety Not

assessment

SECTION 16: Other information

Key or legend to abbreviations and acronyms

CLP: Classification according to Regulation (EC) No. 1272/2008 (GHS)

Classification procedure                   Calculation method.

Full text of phrases referred to         H220: Extremely flammable gas.

under sections 2 and 3                      H222: Extremely flammable aerosol.

H225: Highly flammable liquid and vapour.

H229: Pressurised container: May burst if heated.

H280: Contains gas under pressure; may explode if heated. H302: Harmful if swallowed.

H315: Causes skin irritation.

H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness.

Further information                           Take notice of the directions of use on the label.

Disclaimer                                        The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its

publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality

specification. The information relates only to the specific material designated and may not be valid for such material used in

combination with any other materials or in any process, unless specified in the text.